This page titled 2.4: Silicate Minerals is shared under a CC BY 4.0 license and was authored, remixed, and/or curated by Steven Earle (BCCampus) via source content that was edited to the style and standards of the LibreTexts platform; a detailed edit history is available upon request. An Introduction to Geology (Johnson, Affolter, Inkenbrandt, and Mosher), { "4.01:_Classification_of_Igneous_Rocks" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "4.02:_Bowens_Reaction_Series" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "4.03:_Magma_Generation" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "4.04:_Partial_Melting_and_Crystallization" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "4.05:_Volcanism" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()" }, { "00:_Front_Matter" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "01:_Understanding_Science" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "02:_Plate_Tectonics" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "03:_Minerals" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "04:_Igneous_Processes_and_Volcanoes" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "05:_Weathering_Erosion_and_Sedimentary_Rocks" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "06:_Metamorphic_Rocks" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "07:_Geologic_Time" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "08:_Earth_History" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "09:_Crustal_Deformation_and_Earthquakes" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "10:_Mass_Wasting" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "11:_Water" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "12:__Coastlines" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "13:_Deserts" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "14:_Glaciers" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "15:_Global_Climate_Change" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "16:_Energy_and_Mineral_Resources" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "zz:_Back_Matter" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()" }, [ "article:topic", "showtoc:no", "license:ccbyncsa", "authorname:johnsonaffolterinkenbmosher" ], https://geo.libretexts.org/@app/auth/3/login?returnto=https%3A%2F%2Fgeo.libretexts.org%2FBookshelves%2FGeology%2FBook%253A_An_Introduction_to_Geology_(Johnson_Affolter_Inkenbrandt_and_Mosher)%2F04%253A_Igneous_Processes_and_Volcanoes%2F4.01%253A_Classification_of_Igneous_Rocks, \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}}}\) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash{#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)\(\newcommand{\AA}{\unicode[.8,0]{x212B}}\), Aphanitic/Phaneritic Rock Types with Images. Because only one of the valence electrons of the corner oxygens is shared, the silicon-oxygen tetrahedron has chemically active corners available to form bonds with other silica tetrahedra or other positively charged ions such as Al+3, Fe+2,+3, Mg+2, K+1, Na+1, and Ca+2. They are, however, bonded to the iron and/or magnesium as shown on Figure 2.10. If you dont have glue or tape, make a slice along the thin grey line and insert the pointed tab into the slit. Silicate minerals form the largest group of minerals on Earth, comprising the vast majority of the Earths mantle and crust. The resulting rock is called volcanic glass. Clay minerals form a complex family and are an important component of many sedimentary rocks. Olivine can be either Mg2SiO4 or Fe2SiO4, or some combination of the two (Mg,Fe)2SiO4. Count the number of tetrahedra versus the number of oxygen ions (yellow spheres). Van der Waals bonds differ from covalent and ionic bonds, and exist here between the sandwiches, holding them together into a stack of sandwiches. K-feldspar (KAlSi3O8) has a slightly different structure than that of plagioclase, owing to the larger size of the potassium ion (1.37 ) and because of this large size, potassium and sodium do not readily substitute for each other, except at high temperatures. Minerals in this solid solution series have different mineral names. Chapter 3 Intrusive Igneous Rocks. Olivine is the primary mineral component in mantle rock such as peridotite and basalt. Other sheet silicates include serpentine and chlorite, found in metamorphic rocks. This allows them to substitute for each other in some silicate minerals. Quartz contains only silica tetrahedra. The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. As already noted, the 2 ions of iron and magnesium are similar in size (although not quite the same). Arndt, N. T. Chapter 1 Archean Komatiites. Referring to a silicate mineral that contains iron and or magnesium. Intrusive rocks, forming underground with larger, stronger crystals, are more likely to last. In quartz (SiO2), the silica tetrahedra are bonded in a perfect three-dimensional framework. For each one, indicate whether or not it is a ferromagnesian silicate. Rocks labeled as 'granite' in laymen applications can be several other rocks, including syenite, tonalite, and monzonite. Plutons can have irregular shapes, but can often be somewhat round. Silicate minerals are classified as being either ferromagnesian or non-ferromagnesian depending on whether or not they have iron (Fe) and/or magnesium (Mg) in their formula. Feldspars are mostly silica with aluminum, potassium, sodium, and calcium. These ions have similar ionic sizes, which allows many possible substitutions among them. One angstrom is 1010 m or 0.0000000001 m. The symbol for an angstrom is . As is the case for iron and magnesium in olivine, there is a continuous range of compositions (solid solution series) between albite and anorthite in plagioclase. Fe2+ is known as ferrous iron. As already noted, the +2 ions of iron and magnesium are similar in size (although not quite the same). If you dont have glue or tape, make a slice along the thin grey line and insert the pointed tab into the slit. Silicate minerals are classified as being either ferromagnesian or non-ferromagnesian depending on whether or not they have iron (Fe) and/or magnesium (Mg) in their formula. In amphibole structures, the silica tetrahedra are linked in a double chain that has an oxygen-to-silicon ratio lower than that of pyroxene, and hence still fewer cations are necessary to balance the charge. CC BY. Classification of Igneous Rock Series. The fine-grained texture indicates the quickly cooling lava did not have time to grow large crystals. These are non-ferromagnesian minerals they dont contain any iron or magnesium. Rhyolite is commonly pink and will often have glassy quartz phenocrysts. The Henry Mountains of Utah are a famous topographic landform formed by this process. Exercise: Classifying Igneous Rocks by the Proportion of Dark Minerals The four igneous rocks shown below have differing proportions of ferromagnesian silicates (dark minerals). The oxidized form of an ion of iron (Fe3+). biotite Which of the following is an example of a dark silicate? If you have glue or tape, secure the tabs to the tetrahedron to hold it together. Rhyolite refers to the volcanic and felsic igneous rocks and granite refer to intrusive and felsic igneous rocks. Biotite mica has more iron and magnesium and is considered a ferromagnesian silicate mineral. This single-chain crystalline structure bonds with many elements, which can also freely substitute for each other. It is commonly grey and porphyritic. The names pyroxene, amphibole, mica, and feldspar can be confusing at first, as these are technically names of mineral families and not names of a specific mineral. 3. The large crystals are called phenocrysts and the fine-grained matrix is called the groundmass or matrix. Fe3+ is known as ferric iron. A very common family of framework silicate minerals. The mineral quartz is made up entirely of silica tetrahedra, and some forms of quartz are also known as silica. One type of clay, kaolinite, has a structure like an open-faced sandwich, with the bread being a single layer of silicon-oxygen tetrahedra and a layer of aluminum as the spread in an octahedral configuration with the top oxygens of the sheets. Since the silicon ion has a charge of 4 and each of the four oxygen ions has a charge of 2, the silica tetrahedron has a net charge of 4. The dikes may be intruding over millions of years, but since they may be made of similar material, they would be appearing to be formed at the same time. The three main feldspar minerals are potassium feldspar, (a.k.a. 3.4 Classification of Igneous Rocks - Physical Geology One theory is the overriding rock gets shouldered aside, displaced by the increased volume of magma. Ferro means iron and magnesian refers to magnesium. It has also been proposed that diapirs are not a real phenomenon, but just a series of dikes that blend into each other. Examples of rhyolite include several lava flows in Yellowstone National Park and the altered rhyolite that makes up the Grand Canyon of the Yellowstone. Since the silicon ion has a charge of +4 and each of the four oxygen ions has a charge of 2, the silica tetrahedron has a net charge of 4. The building block of all of these minerals is the silica tetrahedron, a combination of four oxygen atoms and one silicon atom. A stock is a type of pluton with less surface exposure than a batholith and may represent a narrower neck of material emerging from the top of a batholith. Examples include gold (Au), silver (Ag), platinum (Pt), sulfur (S), copper (Cu), and iron (Fe). 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Affolter, Paul Inkenbrandt, & Cam Mosher. 2.4 Silicate Minerals - Physical Geology - opentextbc.ca Ferromagnesian Silicates are silicates with iron (Fe) and/or magnesium (Mg) in their structure. 2.4 Silicate Minerals - Physical Geology | 2.4 Silicate Minerals 3.4 Non-silicate Minerals Figure 3.31: Hanksite, Na22K(SO4)9(CO3) . If a Na+ ion substitutes for a Ca+2 ion, it creates an unequal charge that must be balanced by other ionic substitutions elsewhere in the crystal. A double-chain ferromagnesian silicate mineral (e.g., hornblende). If you have glue or tape, secure the tabs to the tetrahedron to hold it together. Instead, these minerals aremade of other elements in other chemical arrangements. Non-ferromagnesian Silicates are silicate minerals without substantial Fe and Mg in their crystalline structure. Together with quartz, these minerals are classified as framework silicates. A number of minerals and their formulas are listed below. Olivine, pyroxene, amphibole,biotite, and garnet are all examples. What is example of non silicate mineral? The bonds in a silica tetrahedron have some of the properties of covalent bonds and some of the properties of ionic bonds. The carbonate minerals are much simpler structurally than the silicates. The Journal of Geology 39, 5467 (1931). are unstable in this environment and are at least partly altered or dissolved, releasing elements that are removed from the system or form clays, chlorites, and other authigenic minerals in the precursor peat. In fact, the ions that are common in silicate minerals have a wide range of sizes, as depicted in Figure 3.1.3. Iron and magnesium in the olivine family indicate a solid solution forming a compositional series within the mineral group which can form crystals of all iron as one end member and all mixtures of iron and magnesium in between to all magnesium at the other end member. In some cases, extrusive lava cools so rapidly it does not develop crystals at all. A ferromagnesian sheet silicate mineral, typically present as fine crystals and forming from the low-temperature metamorphism of mafic rock. Fe3+ is known as ferric iron. The non-metallic and poorly-reactive mineral carbon is often found as a native element, such as graphite and diamonds. Granite is a good approximation for the continental crust, both in density and composition. This should give you the ratio of Si to O in double-chain silicates (e.g., amphibole). Biotite mica has more iron and magnesium and is considered a ferromagnesian silicate mineral. Minerals within the same family tend to share common structures, but each individual mineral is distinguished by its chemical formula. In muscovite mica, the only cations present are aluminum and potassium; hence it is a non-ferromagnesian silicate mineral. Other rarer elements with similar properties to iron or magnesium, like manganese (Mn), can substitute into the olivine crystalline structure in small amounts. In mica structures, the silica tetrahedra are arranged in continuous sheets, where each tetrahedron shares three oxygen anions with adjacent tetrahedra. The structure of pyroxene is more permissive than that of olivinemeaning that cations with a wider range of ionic radii can fit into it. Significant examples include galena (lead sulfide), sphalerite (zinc sulfide), pyrite (iron sulfide, sometimes called "fool's gold"), and chalcopyrite (iron-copper sulfide). Dikes are therefore discordant intrusions, not following any layering that was present. Ionic radii are critical to the composition of silicate minerals, so well be referring to this diagram again. These tiny crystals can be viewed under a petrographic microscope [1]. 2. Chapters 2 Summary. A silicate mineral in which the silica tetrahedra are made up of sheets.
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